Dr. Philippe P. Lainé is currently a CNRS Senior Scientist (Research Director) at the ITODYS laboratory, University Paris Cité, France. He graduated from Sorbonne University (Pierre and Marie Curie campus, Paris) and earned his Ph.D. in 1993 from Paul Sabatier University, Toulouse, under the supervision of Prof. J.-P. Launay. He subsequently completed postdoctoral research with Profs. A. von Zelewsky and P. Belser at the University of Fribourg, and with Prof. G. Calzaferri at the University of Bern, Switzerland. As a molecular chemist, his primary research interests focus on molecular and supramolecular transduction for energy and information.
Cliquez ici pour en savoir plus
TOPIC: MOLECULAR-LEVEL ENERGY PROCESSING
ARTIFICIAL PHOTOSYNTHESIS – THE “CHARGE POOL” FUNCTION (Electrochemistry)
THE “STRUCTRONIC” PARADIGM
“The Structronic Concept: Harnessing Carbon–Carbon Chemical Bonding for Electron Storage and Related Applications” É. Brémond, M. Hromadová and P. P. Lainé* ChemElectroChem., (2025), 12, e202500037; DOI: 10.1002/celc.202500037
“Are Redox-active Centers Bridged by Saturated Flexible Linkers Systematically Electrochemically Independent?” E. Vaněčková, M. Dahmane, J. Forté, S. Cherraben, X.-Q. Pham, R. Sokolová, É. Brémond,* M. Hromadová* and P. P. Lainé* Angew. Chem. Int. Ed., (2024), 63, e202406299; DOI: 10.1002/anie.202406299
“Recent advances in electrochemistry of pyridinium-based electrophores: A structronic approach.” M. Hromadová,* and P. P. Lainé* Curr. Opin. Electrochem., (2022), 34, 100996, DOI: 10.1016/j.coelec.2022.100996
“On the Supra-LUMO Interaction: Case Study of a Sudden Change of Electronic Structure as a Functional Emergence” A. Gosset, Š. Nováková Lachmanová, S. Cherraben, G. Bertho, J. Forté, C. Perruchot, H.-P. Jacquot de Rouville, L. Pospíšil, M. Hromadová,* E. Brémond* and P. P. Lainé* Chem. Eur. J., (2021), 27, 17889–17899, DOI: 10.1002/chem.202103136
“Electron Storage System Based on a Two-Way Inversion of Redox Potentials” A. Gosset, L. Wilbraham, Š. Nováková Lachmanová, R. Sokolová, G. Dupeyre, F. Tuyèras, P. Ochsenbein, C. Perruchot, H.-P. Jacquot de Rouville, H. Randriamahazaka,* L. Pospíšil,* I. Ciofini,* M. Hromadová* and P. P. Lainé* J. Am. Chem. Soc., (2020), 142 (11), 5162−5176, DOI: 10.1021/jacs.9b12762
THE “BRANCHED EXPANDED (BI-)PYRIDINIUM” PARADIGM
“Kinetics of Multielectron Transfers and Redox-Induced Structural Changes in N-Aryl-Expanded Pyridiniums: Establishing Their Unusual, Versatile Electrophoric Activity” Š. Lachmanová, G. Dupeyre, J. Tarábek, P. Ochsenbein, C. Perruchot, I. Ciofini,* M. Hromadová,* L. Pospíšil* and P. P. Lainé* J. Am. Chem. Soc., (2015), 137 (35), 11349–11364, DOI: 10.1021/jacs.5b05545
“Single-Step versus Stepwise Two-electron Reduction of Polyarylpyridiniums: Insights from the Steric Switching of Redox Potential Compression” J. Fortage, C. Peltier, C. Perruchot, Y. Takemoto, Y. Teki, F. Bedioui, V. Marvaud, G. Dupeyre, L. Pospísil, C. Adamo, M. Hromadová,* I. Ciofini,* and P. P. Lainé* J. Am. Chem. Soc., (2012), 134 (5), 2691–2705, DOI: 10.1021/ja210024y
“Designing Multifunctional Expanded Pyridiniums: Properties of Branched and Fused Head-to-Tail Bipyridiniums” J. Fortage, C. Peltier, F. Nastasi, F. Puntoriero, F. Tuyèras, S. Griveau, F. Bedioui, C. Adamo, I. Ciofini,* S. Campagna,* and P. P. Lainé* J. Am. Chem. Soc., (2010), 132 (46), 16700–16713, DOI: 10.1021/ja108668h
ARTIFICIAL PHOTOSYNTHESIS – THE PHOTOSENSITIZER FUNCTION (Photoredox catalysis)
“EXPANDED CARBENIUMS”
“Triangulenium Dyes: the Comprehensive Photo-Absorption and Emission Story of a Versatile Family of Chromophores” I. Barsuk, P. P. Lainé, F. Maurel and É. Brémond* Phys. Chem. Chem. Phys., (2020), 22 (36), 20673−20684, DOI: 10.1039/d0cp02990d
“Challenging the [Ru(bpy)3]2+ photosensitizer with a triazatriangulenium robust organic dye for visible light-driven hydrogen production in water” R. Gueret, L. Poulard, M. Oshinowo, J. Chauvin, M. Dahmane, G. Dupeyre, P. P. Lainé,* J. Fortage* and M.-N. Collomb* ACS Catalysis (2018), 8, 3792–3802, DOI: 10.1021/acscatal.7b04000
ARTIFICIAL PHOTOSYNTHESIS – PHOTOINDUCED CHARGE SEPARATION (Photophysics & Photochemistry)
“Ru(II)/Os(II)- & PYRIDINIUM-BASED INORGANIC DYADS”
“Photoinduced Intercomponent Processes in Selectively Addressable Bichromophoric Dyads Made of Linearly Arranged Ru(II) Terpyridine and Expanded Pyridinium Components” F. Puntoriero,* A. Arrigo, A. Santoro, G. La Ganga, F. Tuyèras, S. Campagna,* G. Dupeyre, and P. P. Lainé,* Inorg. Chem. (2019), 58 (9), 5807–5817, DOI: 10.1021/acs.inorgchem.9b00139
“Photoinduced electron transfer in donor-bridge-acceptor assemblies: the case of Os(II)-bis(terpyridine)-(bi)pyridinium dyads” A. Arrigo, A. Santoro, F. Puntoriero, P. P. Lainé and S. Campagna* Coord. Chem. Rev., (2015), 304–305, 109–116, DOI: 10.1016/j.ccr.2014.09.019
“Molecular Dyads of Ru(II)– or Os(II)–Bis(terpyridine) Chromophores and Expanded Pyridinium Acceptors. Equilibration between MLCT and Charge-Separated Excited States” J. Fortage, F. Tuyèras, G. Dupeyre, V. Marvaud, P. Ochsenbein, I. Ciofini, M. Hromadová, L. Pospísil, A. Arrigo, E. Trovato, F. Puntoriero,* P. P. Lainé* and S. Campagna* Inorg. Chem., (2013), 52 (20), 11944–11955, DOI: 10.1021/ic401639g
“Photoinduced Electron Transfer in Os(terpyridine)-biphenylene-(bi)pyridinium Assemblies” J. Fortage, F. Puntoriero,* F. Tuyèras, G. Dupeyre, A. Arrigo, I. Ciofini, P. P. Lainé* and S. Campagna* Inorg. Chem., (2012), 51 (9), 5342–5352, DOI: 10.1021/ic300297p
“Conformationally Gated Photoinduced Processes within Photosensitizer – Acceptor Dyads Based on Ruthenium(II) and Osmium(II) Polypyridyl Complexes with an Appended Pyridinium Group” P. P. Lainé*, S. Campagna and F. Loiseau, Coord. Chem. Rev., (2008), 252 (23-24), 2552–2571, DOI: 10.1016/j.ccr.2008.05.007
“Conformationally Gated Photoinduced Processes within Photosensitizer-Acceptor Dyads Based on Osmium(II) Complexes with Triarylpyridinio-Functionalized Terpyridyl Ligands. Insights from Theoretical Analysis.” P. P. Lainé*, F. Loiseau, S. Campagna, I. Ciofini and C. Adamo*, Inorg. Chem., (2006), 45 (14), 5538–5551, DOI: 10.1021/ic060679t
“Conformationally Gated Photoinduced Processes within Photosensitizer-Acceptor Dyads Based on Osmium(II) Complexes with Triarylpyridinio-Functionalized Terpyridyl Ligands. Insights from Experimental Study.” P. P. Lainé*, F. Bedioui, F. Loiseau, C. Chiorboli and S. Campagna*, J. Am. Chem. Soc., (2006), 128 (23), 7510–7521, DOI: 10.1021/ja058357w
“Theoretical Modelling of Photoactive Molecular Systems: Insights Using the Density Functional Theory.” I. Ciofini*, P. P. Lainé, F. Bedioui, C. A. Daul and C. Adamo, CR Chimie, (2006), 9 (2), 226–239, DOI: 10.1016/j.crci.2005.03.023
“Photoinduced Processes Within Compact Dyads Based on Triphenylpyridinium-Functionalized Bipyridyl Complexes of Ruthenium(II).” P. P. Lainé*, I. Ciofini, P. Ochsenbein, E. Amouyal, C. Adamo and F. Bedioui, Chem. Eur. J., (2005), 11, 3711–3727, DOI: 10.1002/chem.200401150
“Photoinduced Intramolecular Electron Transfer in Ruthenium and Osmium Polyads : Insights from Theory.” I. Ciofini, P. P. Lainé, F. Bedioui and C. Adamo* J. Am. Chem. Soc., (2004), 126 (34), 10763–10777, DOI: 10.1021/ja0482278
“Triarylpyridinium-Functionalized Terpyridyl Ligands for Photosensitized Supramolecular Architectures : Intercomponent Coupling and Photoinduced Processes.” P. Lainé*, F. Bedioui, E. Amouyal, V. Albin and F. Berruyer-Penaud, Chem. Eur. J., (2002), 8 (14), 3162–3176. DOI: 10.1002/1521-3765(20020715)8:14<3162::AID-CHEM3162>
“A New Class of Functionalized Terpyridyl ligands as Building Blocks for Photosensitized Supramolecular Architectures. Synthesis, Structural, and Electronic Characterizations.” P. Lainé*, F. Bedioui, P. Ochsenbein, V. Marvaud, M. Bonin and E. Amouyal, J. Am. Chem. Soc., (2002), 124 (7), 1364–1377, DOI: 10.1021/ja011069p
“Photophysical Properties of Osmium(II) Complexes with the Novel 4’-p-phenylterpyridine-triarylpyridinium Ligand” P. Lainé* and E. Amouyal, Chem. Commun., (1999), 935–936, DOI: 10.1039/A901237K
“PHYSICAL ORGANIC CHEMISTRY OF EXPANDED PYRIDINIUMS”
“Tictoid Expanded Pyridiniums: Assessing Structural, Electrochemical, Electronic and Photophysical Features” J. Fortage, F. Tuyèras, C. Peltier, G. Dupeyre, A. Calboréan, F. Bedioui, P. Ochsenbein, F. Puntoriero, S. Campagna,* I. Ciofini,* and P. P. Lainé* J. Phys. Chem. A, (2012), 116 (30), 7880–7891, DOI: 10.1021/jp3043158
“Theoretical Insights into Branched and Fused Expanded Pyridiniums by the Means of Density Functional Theory” C. Peltier, C. Adamo, P. P. Lainé,* S. Campagna, F. Puntoriero and I. Ciofini* J. Phys. Chem. A, (2010), 114 (32), 8434–8443, DOI: 10.1021/jp104439q
“Expanded Pyridiniums: Bis-cyclization of Branched Pyridiniums into Their Fused Polycyclic and Positively Charged Derivatives – Assessing the Impact of Pericondensation on Structural, Electrochemical, Electronic and Photophysical Features” J. Fortage, F. Tuyèras, P. Ochsenbein, F. Puntoriero, F. Nastasi, S. Campagna,* S. Griveau, F. Bedioui, I. Ciofini and P. P. Lainé* Chem. Eur. J., (2010), 16 (36), 11047–11063, DOI: 10.1002/chem.201000504
“Environmental effects on electronic absorption spectra using DFT: an organic and positively charged fused polycyclic chromophore as a case study” C. Peltier, P. P. Lainé, G. Scalmani, M. J. Frisch, C. Adamo* and I. Ciofini* J. Mol. Struct. – THEOCHEM, (2009), 914, 94–99, DOI: 10.1016/j.theochem.2009.05.001
“PHOTOVOLTAICS – DYE-SENSITIZED SOLAR CELLS & RELATED TOPICS”
“Modeling Dye-Sensitized Solar Cells: from Theory to Experiment” T. Le Bahers,* T. Pauporté, P. P. Lainé, F. Labat, C. Adamo* and I. Ciofini* J. Phys. Chem. Lett., (2013), 4 (6), 1044–1050, DOI: 10.1021/jz400046p
“Theoretical Procedure for Optimizing Dye-Sensitized Solar Cells: From Electronic Structure to Photovoltaic Efficiency” T. Le Bahers, F. Labat, T. Pauporté,* P. P. Lainé* and I. Ciofini* J. Am. Chem. Soc., (2011), 133 (20), 8005–8013, DOI: 10.1021/ja201944g
“Ruthenium(II) complexes with new large-surface ligands based on electron-accepting expanded pyridiniums: insights from Density Functional Theory” S. Zeroual, N. Bouet, F. Tuyèras, C. Peltier, N. Ouddai, P. Ochsenbein, C. Adamo, P. P. Lainé* and I. Ciofini* Theor. Chem. Acc., (2012), 131 (2), 1107, DOI: 10.1007/s00214-012-1107-0
“Spectral Properties of Bipyridyl Ligands by Time Dependent Density Functional Theory.” F. Labat, P. P Lainé, I. Ciofini* and C. Adamo, Chem. Phys. Lett., (2006), 417 (4–6), 445–451, DOI: 10.1016/j.cplett.2005.10.066
ARTIFICIAL PHOTOSYNTHESIS – ZEOLITES AS HOST FRAMEWORKS
“Convenient Preparation of Close-Packed Monograin Layers of Pure Zeolite A Microcrystals” P. Lainé, R. Seifert, R. Giovanoli and G. Calzaferri*, New J. Chem., (1997), 21 (4), 453–460, DOI : 10.1002/chin.199735014
“Vibrations of H8Si8O12, D8Si8O12 and H10Si10O15 as Determined by INS, IR and Raman Experiments” C. Marcolli, P. Lainé, R. Bühler, G. Calzaferri* and J. Tomkinson, J. Phys. Chem. B, (1997), 101 (7), 1171–1179, DOI: 10.1021/jp962742d
“Limits of the In Situ Synthesis of Tris(2,2′-bipyridine)-Ruthenium(II) in the Supercages of Zeolite Y” P. Lainé, M. Lanz and G. Calzaferri*, Inorg. Chem., (1996), 35 (12), 3514–3518, DOI: 10.1021/ic9600339
TOPIC: MOLECULAR-LEVEL INFORMATION PROCESSING
“SINGLE-MOLECULE BREAK-JUNCTION APPROACH”
“Environmental Control of Single-Molecule Junction Evolution and Conductance. Case Study of Expanded Pyridinium Wiring.” Š. Nováková Lachmanová, V. Kolivoška, J. Šebera, J. Gasior, G. Mészáros, G. Dupeyre, P. P. Lainé* and M. Hromadová* Angew. Chem Int. Ed., (2021), 60 (9), 4732–4739, DOI: 10.1002/anie.202013882
“Adsorption of Expanded Pyridinium Molecules at the Electrified Interface and Its Effect on the Electron-Transfer Process” Š. Nováková Lachmanová; G. Dupeyre; P. P Lainé and M. Hromadova* Langmuir (2018) , 34 (22), 6405–6412, DOI: 10.1021/acs.langmuir.8b00671
“Correlation of Electrochemical Properties of Expanded Pyridinium Compounds with their Single Molecule Conductance ” Š. Nováková Lachmanová, J. Šebera, V. Kolivoška, J. Gasior, G. Mészáros, G. Dupeyre, P. P Lainé* and M. Hromadova* Electrochim. Acta, (2018) , 264, 301–311, DOI: 10.1016/j.electacta.2018.01.094
“SINGLE-MOLECULE MAGNETS & MOLECULAR SPINTRONICS”
“A New Versatile Class of Hetero-tetra-metallic Assemblies: Highlighting Single-molecule Magnet Behaviour” N. Bridonneau, L.-M. Chamoreau, P. P. Lainé, W. Wernsdorfer and V. Marvaud* Chem. Commun., (2013), 49 (82), 9476–9478, DOI: 10.1039/C3CC45037F
“Intramolecular Spin Alignment within Mono-Oxidized and Photo-Excited Anthracene-Based p-Radicals as Prototypical Photomagnetic Molecular Devices: Relationships Between Electrochemical, Photophysical and Photochemical Control Pathways” I. Matsumoto, I. Ciofini, P. P. Lainé and Y. Teki* Chem. Eur. J., (2009), 15 (42), 11210–11220, DOI: 10.1002/chem.200900350
“Reaching Optimal Light-Induced Intramolecular Spin Alignment within Photo-Magnetic Molecular Devices Prototypes” I. Ciofini*, C. Adamo, Y. Teki, F. Tuyèras and P. P. Lainé* Chem. Eur. J., (2008), 14 (36), 11385–11405, DOI: 10.1002/chem.200801405
“Intramolecular Spin Alignment in Photo-Magnetic Molecular Devices: a Theoretical Study.” I. Ciofini*, P. P. Lainé*, M. Zamboni, C. A. Daul, V. Marvaud and C. Adamo, Chem. Eur. J., (2007), 13 (19), 5360–5377, DOI: 10.1002/chem.200700015
“MOLECULAR ELECTRONICS : MIXED-VALENT DINUCLEAR COMPOUNDS”
“Electron Transfer Through Norbornadiene and Quadricyclane Moieties as a Model for Molecular Switching” P. Lainé, V. Marvaud, A. Gourdon, J.-P. Launay*, R. Argazzi and C. A. Bignozzi, Inorg. Chem., (1996), 35 (3), 711–714, DOI: 10.1021/ic9507225
“Pronounced Electronic Coupling in Rigidly Connected N,C,N-Coordinated Diruthenium Complexes over a Distance up to 20 Å” M. Beley, S. Chodorowski-Kimmes, J.-P. Collin, P. Lainé, J.-P. Launay* and J.-P. Sauvage*, Angew. Chem., Int. Ed. Engl., (1994), 33 (17), 1775–1778, DOI: 10.1002/anie.199417751
“Long-range Coupling in Mixed-valence Diruthenium Complexes Containing Bis-terpyridines Ligands of Various Lengths as Bridges” J.-P. Collin, P. Lainé, J.-P. Launay, J.-P. Sauvage and A. Sour, J. Chem. Soc., Chem. Commun., (1993), 5, 434–435, DOI: 10.1039/C39930000434
“MOLECULAR ELECTRONICS – A THEORETICAL STUDY”
“Quantifying electron delocalization in orthogonal channels: theoretical investigation of (4n+2) σ and π aromaticity in [C6I6]2+.” I. Ciofini*, P. P. Lainé and C. Adamo, Chem. Phys. Lett., (2007), 435 (4–6), 171–175, DOI: 10.1016/j.cplett.2006.12.058
“PHOTOBIOLOGICAL & BIOANALYTICAL APPLICATIONS”
“Designing expanded bipyridinium as redox and optical probes for DNA” E. Trovato, M. L. Di Pietro,* A. Giannetto, G. Dupeyre, P. P. Lainé,* F. Nastasi, F. Puntoriero* and S. Campagna Photochem. Photobiol. Sci., (2020), 19, 105–113, DOI: 10.1039/c9pp00418a
“Photochemically Driven Intercalation of Small Molecules into DNA by in situ Irradiation” M. L. Di Pietro, F. Puntoriero, F. Tuyèras, P. Ochsenbein, P. P. Lainé* and S. Campagna* Chem. Commun., (2010), 46, 5169–5171, DOI: 10.1039/c002748k
“Improving Visible Light Sensitization of Luminescent Europium Complexes” P. Kadjane, L. Charbonnière*, F. Camerel, P. P. Lainé and R. Ziessel*, J. Fluoresc., (2008), 18 (1), 119–129, DOI: 10.1007/s10895-007-0250-9
MISCELLANEOUS
“CHEMISTRY & PHYSICAL CHEMISTRY OF PYRIMIDYL-SUBSTITUTED ANTHRACENE FLUOROPHORES”
“Pyrimidyl-substituted anthracene fluorophores: Syntheses, absorption spectra, and photophysical properties” A. Santoro, F. Tuyèras, G. Dupeyre, P. P. Lainé,* I. Ciofini,* F. Nastasi, F. Puntoriero and S. Campagna* Dyes and Pigments (2018) , 159, 619–636, DOI: 10.1016/j.dyepig.2018.07.027
“NON-LINEAR OPTICS”
“Substantial Non-Linear Optical Response of New Polyads Based on Ru and Os Complexes of Modified Terpyridines” M. Konstantaki, E. Koudoumas, S. Couris*, P. Lainé, E. Amouyal* and S. Leach, J. Phys. Chem. B, (2001), 105 (44), 10797–10804, DOI: 10.1021/jp010497e
“COORDINATION CHEMISTRY OF IRON(II) & IRON(III)”
“Chemistry of Iron and Dipicolinic Acid. 4. Mixed-Ligand Complexes of Iron(III) and Related Compounds” P. Lainé, A. Gourdon* and J.-P. Launay, Inorg. Chem., (1995), 34 (21), 5156–5165, DOI: 10.1021/ic00125a012
“Chemistry of Iron with Dipicolinic Acid. 3. Heptacoordinated Iron in [(dipicH)2FeII(OH2)] and [(dipic)2FeII2(OH2)6]•2dipicH2” P. Lainé, A. Gourdon*, J.-P. Launay and J.-P. Tuchagues, Inorg. Chem., (1995), 34 (21), 5150–5155, DOI: 10.1021/ic00125a011
“Chemistry of Iron with Dipicolinic Acid. 2. Bridging Role of Carboxylate Groups in Solid State Structures” P. Lainé, A. Gourdon* and J.-P. Launay, Inorg. Chem., (1995), 34 (21), 5138–5149, DOI: 10.1021/ic00125a010
“Chemistry of Iron with Dipicolinic Acid. 1. Mononuclear Complexes of Iron(II) or Iron(III)” P. Lainé, A. Gourdon* and J.-P. Launay, Inorg. Chem., (1995), 34 (21), 5129–5137, DOI: 10.1021/ic00125a009
“SINGLE-CRYSTAL X-RAY DIFFRACTION – MOLECULAR STRUCTURE”
“Bicyclo[2.2.3]hepta-2,5-diene-2,3-dicarboxamide, C9H10N2O2” A. Gourdon* and P. Lainé, Acta Cryst. C, (1994), 50, 414–415, DOI: 10.1107/S0108270193002021